New Mixed??Ligand ReV Complexes with Bis (2??mercaptoethyl) Sulfide and Functionalized Thioimidazolyl Ligands

…, JDG Correia, Â Domingos, I Santos

Index: Palma, Elisa; Correia, Joao D. G.; Domingos, Angela; Santos, Isabel European Journal of Inorganic Chemistry, 2002 , # 9 p. 2402 - 2407

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Citation Number: 8

Abstract

Abstract The preparation of the mixed-ligand Re V complexes [Re (O)(κ 3-SSS)(κ 1- Simz)](1),[Re (O)(κ 3-SSS)(κ 1-Simz)]· HCl (2) and [Re (O)(κ 3-SSS)(κ 1-SimzCOGlyGly)](3) are described. These [3+ 1] type compounds are stabilized by tridentate bis (2- mercaptoethyl) sulfide (HSSSH) and by monodentate functionalized thioimidazolyl ligands. Complexes 1, 2 and 3 were fully characterized by IR and 1 H NMR spectroscopy, and by X ...