Effects of metal ions on physicochemical properties and redox reactivity of phenolates and phenoxyl radicals: mechanistic insight into hydrogen atom abstraction by …

S Itoh, H Kumei, S Nagatomo, T Kitagawa…

Index: Itoh; Kumei; Nagatomo; Kitagawa; Fukuzumi Journal of the American Chemical Society, 2001 , vol. 123, # 10 p. 2165 - 2175

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Citation Number: 66

Abstract

Phenolate and phenoxyl radical complexes of a series of alkaline earth metal ions as well as monovalent cations such as Na+ and K+ have been prepared by using 2, 4-di-tert-butyl-6-(1, 4, 7, 10-tetraoxa-13-aza-cyclopentadec-13-ylmethyl) phenol (L1H) and 2, 4-di-tert-butyl-6-(1, 4, 7, 10, 13-pentaoxa-16-aza-cyclooctadec-16-ylmethyl) phenol (L2H) to examine the effects of the cations on the structure, physicochemical properties and redox reactivity of the ...