e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Synthesis of the isomeric phenols of benz [a] anthracene from benz [a] anthracene

PP Fu, C Cortez, KB Sukumaran…

Index: Fu,P.P. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 24 p. 4265 - 4271

Full Text: HTML

Citation Number: 26

Abstract

Novel and convenient syntheses of seven isomeric phenols of benz [a] anthracene El-, 2-, 3- , 8-, 9-, lo-, and 11-HO-BA) from the parent polycyclic hydrocarbon are described. These syntheses demonstrate the feasibility of introduction of functional groups into polycyclic arene ring positions not prone to direct substitution through initial regioselective hydrogenation (or metal-ammonia reduction), followed by appropriate synthetic ...

8,9,10,11-Tetrahydrobenzo(B)phenanthren-8-ol Structure

8,9,10,11-Tetra...

~%

10,11-dihydrobenzo[a]anthracene Structure

10,11-dihydrobe...

Benz[a]anthracen-8(9H)-one, 10,11-dihydro- Structure

Benz[a]anthrace...

~%

10,11-dihydrobenzo[a]anthracene Structure

10,11-dihydrobe...

9,10-dihydro-8H-benzo[a]anthracen-11-one Structure

9,10-dihydro-8H...

~%

benzo[a]anthracen-11-ol Structure

benzo[a]anthrac...

8,9,10,11-tetrahydrobenz(a)anthracene Structure

8,9,10,11-tetra...

~%

benzo[a]anthracen-11-ol Structure

benzo[a]anthrac...

8,9-dihydrotetraphen-11-yl acetate Structure

8,9-dihydrotetr...

~%

benzo[a]anthracen-11-ol Structure

benzo[a]anthrac...

Benz(a)anthracene Structure

Benz(a)anthracene

~%

1,2,3,4-tetrahydrobenzo[a]anthracene Structure

1,2,3,4-tetrahy...

Benz[a]anthracen-8(9H)-one, 10,11-dihydro- Structure

Benz[a]anthrace...

~%

benzo[a]anthracen-8-ol Structure

benzo[a]anthrac...

1,2,3,4-tetrahydrobenzo[a]anthracene Structure

1,2,3,4-tetrahy...

~%

3,4-Dihydro-1(2H)-tetraphenone Structure

3,4-Dihydro-1(2...

1a,2,3,11b-tetrahydrobenz[5,6]anthra[1,2-b]oxirene Structure

1a,2,3,11b-tetr...

~%

benzo[a]anthracen-9-ol Structure

benzo[a]anthrac...

10,11-dihydrotetraphen-9(8H)-one Structure

10,11-dihydrote...

~%

benzo[a]anthracen-9-ol Structure

benzo[a]anthrac...

10,11-dihydrotetraphen-9-yl acetate Structure

10,11-dihydrote...

~%

benzo[a]anthracen-9-ol Structure

benzo[a]anthrac...

3-Oxo-1,2,3,4,7,12-tetrahydrobenzanthracen Structure

3-Oxo-1,2,3,4,7...

~%

Benz[a]anthracen-3-ol Structure

Benz[a]anthrace...

1,4,7,12-Tetrahydro-benz(a)anthracen Structure

1,4,7,12-Tetrah...

~%

Benz[a]anthracen-3-ol Structure

Benz[a]anthrace...

3-Oxo-1,2,3,4,7,12-tetrahydrobenzanthracen Structure

3-Oxo-1,2,3,4,7...

~%

3-Methoxybenz[a]anthracene Structure

3-Methoxybenz[a...

1,4,7,12-Tetrahydro-benz(a)anthracen Structure

1,4,7,12-Tetrah...

~%

3-Methoxybenz[a]anthracene Structure

3-Methoxybenz[a...

Benz[a]anthracen-3-ol Structure

Benz[a]anthrace...

Dimethyl sulfate Structure

Dimethyl sulfate

~%

3-Methoxybenz[a]anthracene Structure

3-Methoxybenz[a...

1,2,3,4-tetrahydrobenzo[a]anthracene Structure

1,2,3,4-tetrahy...

~%

2,3-dihydro-1H-benzo[a]anthracen-4-one Structure

2,3-dihydro-1H-...

8,9,10,11-tetrahydrobenz(a)anthracene Structure

8,9,10,11-tetra...

~%

9,10-dihydro-8H-benzo[a]anthracen-11-one Structure

9,10-dihydro-8H...