Molecular Crystals and Liquid Crystals

Synthesis and Physical Properties of Poly (Phenylene Vinylene) s having Oligo (Ethylene Oxide) in the Side Chain

T Mihara, T Yada, N Koide

Index: Mihara, Takashi; Yada, Takahiro; Koide, Naoyuki Molecular Crystals and Liquid Crystals, 2004 , vol. 411, p. 421/[1463]-437/[1479]

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Citation Number: 9

Abstract

Oligo (ethylene oxide) chains were introduced into the phenyl ring of the poly (phenylene vinylene)(PPV) derivatives to obtain electronic and ionic conductive liquid crystalline PPV derivatives. Thermal decomposition of all PPV derivatives occurred before isotropic melt. A typical texture of the liquid crystalline phase was not shown but birefringence was observed below the thermal decomposition temperature. Exhibition of a smectic phase for the ...