Organic letters

Encapsulated reagents for nitrosation

GV Zyryanov, DM Rudkevich

Index: Zyryanov, Grigory V.; Rudkevich, Dmitry M. Organic Letters, 2003 , vol. 5, # 8 p. 1253 - 1256

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Citation Number: 38

Abstract

A novel class of stable, mild, and size-shape-selective nitrosating agents for secondary amides is introduced. These are based on reversible entrapment and release of reactive nitrosonium species by calix [4] arenes. The NO+ encapsulation controls the reaction selectivity.