Tetrahedron

The reduction of semipolar linkages by O, O-dialkyl dithiophosphoric acid

S Oae, A Nakanishi, N Tsujimoto

Index: Oae,S. et al. Tetrahedron, 1972 , vol. 28, p. 2981 - 2990

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Citation Number: 29

Abstract

Compounds having a semipolar functional group, generally formulated X→ Y, ie sulfoxide, sulfilimine, sulfonium ylide, pyridine N-oxide, and N-iminopyridinium betaine, were found to react readily with O, O-dialkyl dithiophosphoric acid to afford the corresponding reduction products, sulfide and pyridine.