Dinuclear Copper (II) Complexes with Bis??thiocarbohydrazone Ligands

D Dragancea, AW Addison, M Zeller…

Index: Dragancea, Diana; Addison, Anthony W.; Zeller, Matthias; Thompson, Laurence K.; Hoole, Dushyanthi; Revenco, Mihail D.; Hunter, Allen D. European Journal of Inorganic Chemistry, 2008 , # 16 p. 2530 - 2536

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Citation Number: 7

Abstract

Abstract Copper (II) complexes with substituted bis (salicylaldehyde) thiocarbohydrazones (3-methoxy= H 4 L Me, 3-ethoxy= H 4 L Et), have been synthesized. These ditopic ligands form dinuclear copper (II) complexes containing the ligands in their triplydeprotonated forms. The ligands entail two nonequivalent donor atom sites (ONN and ONS) for copper (II) coordination. Magnetic measurements of the complexes in the temperature range 2–290 ...