Canadian Journal of Chemistry

ESTER HYDRAZONES AS POSSIBLE PRECURSORS TO ALKOXYDIAZOALKANES: II. THE DECOMPOSITION OF ESTER (p-TOLYLSULFONYL) HYDRAZONE …

RJ Crawford, R Raap

Index: Crawford,R.J.; Raap,R. Canadian Journal of Chemistry, 1965 , vol. 43, p. 356 - 368

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Citation Number: 11

Abstract

The thermal and photochemical decomposition of methyl benzoate (p-tolylsulfonyl) hydrazone salts in 1, 2-dimethoxyethane, 1, 2-diethoxyethane, or diglyme gives rise to benzaldehyde dimethyl acetal, methyl benzoate azine (II), meso-1, 2-diphenyl-1, 2- dimethoxyethane, and methyl α-(p-tolylsulfonyl) benzyl ether. The thermal decomposition in the presence of diethyl fumarate produced diethyl 3-methoxy-3-phenyl-trans-1, 2- ...

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