Substituted N, N-Dimethyl-3-(phenylthio)-and-4-(phenylthio) benzylamines

…, V Kmoníček, M Hrubantová, Z Polívka

Index: Sindelar, Karel; Kmonicek, Vojtech; Hrubantova, Marta; Polivka, Zdenek Collection of Czechoslovak Chemical Communications, 1992 , vol. 57, # 1 p. 194 - 203

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Citation Number: 6

Abstract

Abstract (Arylthio) benzoic acids IIa-IIe and VIb-VId were transformed via the acid chlorides to the N, N-dimethylamides which were reduced either with diborane" in situ" or with lithium aluminium hydride to N, N-dimethyl-(arylthio) benzylamines Ia-Ie and Vb-Vd. Leuckart reaction of the aldehydes IX and X with dimethylformamide and formic acid afforded directly the amines Va and Ve. Demethylation of the methoxy compounds Ia and Ve with ...