The Journal of Organic Chemistry

The far-UV photochemistry of five-and six-membered-ring monosilacycloalkenes in alcohols: stereospecific. beta.-cleavage to silyl ethers and stereoselective …

MG Steinmetz, C Yu

Index: Steinmetz, Mark G.; Yu, Changjun Journal of Organic Chemistry, 1992 , vol. 57, # 11 p. 3107 - 3120

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Citation Number: 16

Abstract

Results Direct Photolyses of Silacyclopent-2-ene 9 and Si-lacyclohex-2-ene 10 in Methanol, 2, 2, 2-Trifluoroethanol, and tert-Butyl Alcohol. Preparative direct photolyses of M solutions of 9 and 10 in deoxygenated alcohols at 214 nm gave alkenylsilyl ethers lla-c and 17a-c as the