Tetrahedron letters

Reductive Beckmann fragmentation of α-alkoxycycloalkanone oxime acetates

…, H Yamamoto, M Miyazaki, T Yamanaka, K Takuma…

Index: Fujioka, Hiromichi; Yamamoto, Hideaki; Miyazaki, Makoto; Yamanaka, Takeshi; Takuma, Kazuhiro; Kita, Yasuyuki Tetrahedron Letters, 1991 , vol. 32, # 39 p. 5367 - 5368

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Citation Number: 8

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The title reaction was achieved with Et 3 SiH in the presence of a catalytic amount of CF 3 SO 3 SiMe 3 . The reaction was applied to the synthesis of (±)-exo-brevicomine. ... High trans-selectivity might be rationalized as follows. That is, the counter anion is placed on the opposite side ...