The photochemistry of an aryl pentazole in liquid solutions: the anionic 4-oxidophenylpentazole (OPP)

U Geiger, Y Haas, D Grinstein

Index: Geiger, Uzi; Haas, Yehuda; Grinstein, Dan Journal of Photochemistry and Photobiology A: Chemistry, 2014 , vol. 277, p. 53 - 61

Full Text: HTML

Citation Number: 10

Abstract

Abstract This paper reports a study on the photolysis of an aryl pentazole in solution. 4- Oxidophenylpentazole (OPP) was irradiated in water and in acetonitrile at its first absorption band (320 and 370 nm, respectively) and at 193 nm. 4-Oxidophenylazide (OPA) was also investigated under similar conditions for comparison. NMR and UV–vis absorption spectroscopies of the products show that the major stable products of OPP photolysis in ...