A new rigid sulfur-bridged dithiametacyclophane and its acyclic analogs: direct observation of the transannular bond formation between the three sulfur atoms and …

H Fujihara, JJ Chiu, N Furukawa

Index: Fujihara,H.; Chiu,J.; Furukawa,N. Journal of the American Chemical Society, 1988 , vol. 110, p. 1280

Full Text: HTML

Citation Number: 50

Abstract

Abstract: A new rigid sulfur-bridged dithiametacyclophane, 1, ll-(methanothiomethano)-5H, 7H-dibenzo [b, g][1, 5] dithiocin (l), analogous acyclic trithia compounds, 2, 6-bis [(methylthio) methyl] phenyl phenyl sulfide (7), and the corresponding sulfoxides were prepared by general methods. The transannular bond formation between the three sulfur atoms of 1 was observed in the reaction of sulfide 1 and its sulfoxides (2, 3) with ...