Molybdenum (VI) and molybdenum (V) complexes with N, N'-dimethyl-N, N'-bis (2-mercaptophenyl) ethylenediamine. Electrochemical and electron paramagnetic …

D Dowerah, JT Spence, R Singh…

Index: Dowerah, Dulal; Spence, Jack T.; Singh, Raghuvir; Wedd, Anthony G.; Wilson, Graham L.; et al. Journal of the American Chemical Society, 1987 , vol. 109, # 19 p. 5655 - 5665

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Citation Number: 90

Abstract

Abstract: As models for the molybdenum (VI/V) centers of the molybdenum hydroxylases and related enzymes, MoOzL and MoOClL (LH2= N, N'-dimethyl-N, N'-bis (2-mercaptophenyl) ethylenediamine) have been synthesized. The structure of Mo0, L has been determined by X- ray cr stallography. The compound crystallizes in space group P2,/n, with a= 10.049 (2) A, b= 14.538 (2) A, c= 12.143 (1) 1, p= 103.73 (l)', and 2= 4. Mo02L is six-coordinate with ...