Synthesis of Enantiomerically Pure 1, 2-Disubstituted 2-Selenoamines

…, A Degl'Innocenti, A Capperucci…

Index: Torrente, Esther; Ruano, Jose Luis Garcia; Castro, Ana M. Martin; Degl'Innocenti, Alessandro; Capperucci, Antonella; Frateschi, Lucrezia Phosphorus, Sulfur and Silicon and the Related Elements, 2011 , vol. 186, # 5 p. 1268 - 1273

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Abstract

Abstract Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2- p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-phenyl, 2-aryl (or alkyl)-2-phenylseleno ethylamines by subsequent reactions, which were treatment reactions with t-BuLi and TFA. Supplemental materials are available for this article. Go to ...