Synthesis and solvolysis of 4-substituted nortricyclenes

PJ Chenier, JR McClure…

Index: Chenier,P.J. et al. Journal of Organic Chemistry, 1978 , vol. 43, # 22 p. 4306 - 4310

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Abstract

A number of 4-substituted nortricyclenes (2) have been synthesized, including 4- aminonortricyclene hydrochloride (2a), nortricyclyl-4-carbinol (2f), and its tosylate (2e). The synthesis of these compounds is discussed. Amine hydrochloride 2a was synthesized because of its similarity in structure to 1-aminoadamantane hydrochloride (li, which has antiviral properties against certain influenzas. Tosylate 2e was solvolyzed in acetic acid; ...