Abstract 1-Substituted 3-[3-(methyl/phenyl)-1H-pyrazol-5-yl] thioureas react with the triple bond of dimethyl acetylenedicarboxylate forming (Z)-methyl 2-[(Z)-3-substituted-2-(3- (methyl/phenyl-1H-pyrazol-5-ylimino)-4-oxothiazolidin-5-ylidene) acetates. Rational for these conversations are presented.