The First Stereoselective Total Synthesis of a Naturally Occurring Bioactive Diarylheptanoid,(3R, 6E)??1, 7??Bis (4??hydroxyphenyl) hept??6??en??3??ol, through Two …

J Kashanna, P Jangili, RA Kumar…

Index: Kashanna, Jajula; Jangili, Paramesh; Kumar, Rathod Aravind; Das, Biswanath Helvetica Chimica Acta, 2012 , vol. 95, # 9 p. 1666 - 1671

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Citation Number: 9

Abstract

Abstract The stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid,(3R, 6E)-1, 7-bis (4-hydroxyphenyl) hept-6-en-3-ol, has been accomplished starting from 4-hydroxybenzaldehyde through two different approaches involving Wittig olefination, hydrolytic kinetic resolution of a racemic epoxide, and olefin cross-metathesis reaction as the key steps.

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