Phosphorus, Sulfur, and Silicon

Synthesis of Dichloromethylphosphonates

P Majewski, JF Koszuk

Index: Majewski, Piotr; Koszuk, Jacek F. Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 4 p. 956 - 962

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Abstract

Efficient synthesis of O, O-dialkyl, O-alkyl-N, N-dialkylamido and N, N, N′, N′- tetraalkyldiamido dichloromethylphosphonates via treatment of O, O-dialkyl, O-alkyl-N, N- dialkylamido, and N, N, N′, N′-tetraalkyldiamido trichloromethylphosphonates with diethyl phosphite in the presence of triethylamine in ethanol has been described.