Homolytic aromatic substitution. Part VII. Partial rate factors for the phenylation of tert.-butylbenzene and p-di-tert.-butylbenzene

JIG Cadogan, DH Hey, GH Williams

Index: Cadogan et al. Journal of the Chemical Society, 1954 , p. 3352,3358

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Abstract

The proportions of the three isomeric tert.-butyldiphenyls formed in the phenylation of tert.- butylbenzene are determined by infra-red spectrometry. In addition, competitive experiments are carried out on the action of phenyl radicals derived from benzoyl peroxide on mixtures of