Israel Journal of Chemistry

Planar and Nonplanar Unsaturation. Preparation, Properties and Molecular??Orbital Characterization of Some Fluoro??Derivatives of Anthracene and Anthraquinone

AY Meyer, A Goldblum

Index: Meyer,A.Y.; Goldblum,A. Israel Journal of Chemistry, 1973 , vol. 11, p. 791 - 804

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Citation Number: 10

Abstract

Abstract Several fluoroanthracenes (I-III) and fluoroanthraquinones (IV-VII) were prepared, and their PMR and UV spectra, as well as dipole moments, recorded. These are discussed in terms of molecular-orbital data, both of the pi-electronic type (including nonbonding 2p- orbitals) and of the all-valence-electron type. PMR signals can be assigned on the basis of such calculations. The interpretation of UV spectra is straightforward in the case of ...