Tetrahedron letters

Copper-catalyzed allylations of o-vinylbenzylzirconocene intermediate

Y Ikeuchi, T Taguchi, Y Hanzawa

Index: Ikeuchi, Yutaka; Taguchi, Takeo; Hanzawa, Yuji Tetrahedron Letters, 2004 , vol. 45, # 19 p. 3717 - 3720

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Citation Number: 6

Abstract

Benzylzirconocene intermediate, which was readily prepared by the reaction of o- alkoxymethylstyrene withCp2Zr'under mild conditions, reacted with allylic halides or phosphates in the presence of catalytic amount of CuCl to give allylated products in good yields.