Synthesis of alkyl β-glycosides of 6-(N-acetylmuramoyl-L-alanyl-D-isoglutaminylamino) hexanoic acid and its 4-aminobutyl ester

VO Kur'yanov, VV Tsikalov, AE Zemlyakov…

Index: Kur'yanov, V.O.; Tsikalov, V.V.; Zemlyakov, A.E.; Chirva, V.Ya. Chemistry of Natural Compounds, 1994 , vol. 30, # 3 p. 390 - 394 Khimiya Prirodnykh Soedinenii, 1994 , # 3 p. 424 - 429

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Abstract

Abstract The synthesis has been effected of alkyl β-glycosides containing spacers with amino and carboxy groups at the end. As “prespacers” we used benzyl and 4-azidobutyl esters of 6-(L-alanyl-D-isoglutaminylamino) hexanoic acid. The use of the butyl and hexadecyl β-glycosides of N-acetylmuramic acid has enabled us to obtain glycopeptides with different hydrophilic—lipophilic balances.