The synthesis of phosphonate ester containing fluorinated vinyl ethers

SD Pedersen, W Qiu, ZM Qiu, SV Kotov…

Index: Pedersen, Scot D.; Qiu, Weiming; Qiu, Zai-Ming; Kotov, Stefan V.; Burton, Donald J. Journal of Organic Chemistry, 1996 , vol. 61, # 23 p. 8024 - 8031

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Citation Number: 14

Abstract

Three novel perfluorovinyl ethers containing phosphonate ester groups, diethyl 1, 1, 2, 2, 3, 3, 5, 6, 6-nonafluoro-4-oxa-5-hexenylphosphonate,(EtO) 2P (O)(CF2) 3OCF CF2 (1), diethyl 1, 1, 2, 2, 4, 5, 5-heptafluoro-3-oxa-4-pentenylphosphonate,(EtO) 2P (O)(CF2) 2OCF CF2 (2), and diethyl 1, 1, 2, 2, 4, 5, 5, 7, 8, 8-decafluoro-4-trifluoromethyl-3, 6-dioxa-7- octenylphosphonate, CF2 CFOCF2CF (CF3) O (CF2) 2P (O)(OEt) 2 (3), have been ...