Assembly and binding properties of osmate ester-bridged binuclear macrocycles

KS Jeong, YL Cho, SY Chang, TY Park…

Index: Jeong, Kyu-Sung; Cho, Young Lag; Chang, Sung-Youn; Park, Tae-Yoon; Song, Jung Uk Journal of Organic Chemistry, 1999 , vol. 64, # 26 p. 9459 - 9466

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Citation Number: 45

Abstract

Osmium (VI)-bridged macrocycles 1a-c, 2, and 3 assemble spontaneously when osmium tetraoxide, olefins, and L-shaped bispyridyl ligands are mixed in CHCl3. The macrocycles possess well-defined square or rectangular cavities enclosed by aryl walls and act as host ...