Ir-catalyzed hydrosilylation reaction of allyl acetate with octakis (dimethylsiloxy) octasilsesquioxane and related hydrosilanes

M Igarashi, T Matsumoto, T Kobayashi, K Sato…

Index: Igarashi, Masayasu; Matsumoto, Tomohiro; Kobayashi, Toshiaki; Sato, Kazuhiko; Ando, Wataru; Shimada, Shigeru; Hara, Masanao; Uchida, Hiroshi Journal of Organometallic Chemistry, 2014 , vol. 752, p. 141 - 146

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Citation Number: 3

Abstract

Abstract Hydrosilylation reaction of allyl acetate (AA) with octakis (dimethylsiloxy) octasilsesquioxane [(HSiMe 2 O) 8 (SiO 1.5) 8] was efficiently catalyzed by chloro (1, 5- cyclooctadiene) iridium (I) dimer [Ir (μ-Cl)(COD)] 2. The effects of the catalyst amounts and the reaction conditions on the conversion and the product selectivity were investigated.[Ir (μ- Cl)(COD)] 2 catalyst was also applied to the hydrosilylation reaction of AA with other ...