Design and reactivity of topologically unique, chiral phosphonamides. Remarkable diastereofacial selectivity in asymmetric olefination and alkylation

S Hanessian, D Delorme, S Beaudoin…

Index: Journal of the American Chemical Society, , vol. 106, # 19 p. 5754 - 5756

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Citation Number: 140

Abstract

... 0 1984 American Chemical Society ... (1 1) Deslongchamps, P. 'Stereoelectronic Effects in Organic Chemistry"; Baldwin, J. E ... The potential reversibility of the ole- fination reaction via intermediate @-alkoxyphosphonamides prompted us to probe the reactivity of the phosphonamide ...