Preparation of a thallium (I) diazotate. Structure, physicochemical characterization, and conversion to novel N-nitroso compounds

LK Keefer, SM Wang, T Anjo, JC Fanning…

Index: Keefer, Larry K.; Wang, Shui-mei; Anjo, Takako; Fanning, James C.; Day, Cynthia S. Journal of the American Chemical Society, 1988 , vol. 110, # 9 p. 2800 - 2806

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Citation Number: 10

Abstract

Abstract: Thallium (1)(E)-methanediazotate (4) has been prepared and characterized. In contrast to previously reported methanediazotates, 4 is a highly crystalline material whose physical properties suggest a considerable degree of covalency: it is readily soluble in certain nonpolar solvents; it melts reversibly at a low temperature; it is monomeric and nonconducting in chloroform solution; and ions corresponding to the formula TI (CH3N20)' ...