Energy barrier for 1, 2-hydrogen migration in benzylchlorocarbene

MTH Liu

Index: Liu, Michael T. H. Journal of the Chemical Society, Chemical Communications, 1985 , # 14 p. 982 - 984

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Citation Number: 18

Abstract

The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy of 6.4 kcal mol–1 (26.8 kJ mol–1) was obtained for the 1, 2-H migration in benzylchlorocarbene.

Rearrangement of alkylchlorocarbenes: 1, 2-H shift in free c...

[Bonneau, Roland; Liu, Michael T. H.; Kim, Kyu Chul; Goodman, Joshua L. Journal of the American Chemical Society, 1996 , vol. 118, # 16 p. 3829 - 3837]

Benzylchlorocarbene: kinetic parameters for 1, 2-hydrogen mi...

[Liu, Michael T. H.; Bonneau, Roland Journal of the American Chemical Society, 1990 , vol. 112, # 10 p. 3915 - 3919]

Reactive intermediates in the photolysis and thermolysis of ...

[Liu, Michael T. H.; Chishti, Najmul H.; Tencer, Michael; Tomioka, Hideo; Izawa, Yasuji Tetrahedron, 1984 , vol. 40, # 5 p. 887 - 892]

Benzylchlorocarbene: a new ambiphile

[Liu, Michael T. H.; Suresh, Raghava, V.; Soundararajan, N.; Vessey, Edward G. Journal of the Chemical Society, Chemical Communications, 1989 , # 1 p. 12 - 14]