Electron transfer processes. 30. Participation of anions of dialkyl phosphites and thiophosphites in aliphatic SRN1 reactions

…, F Ros, J Hershberger, H Tashtoush

Index: Russel, Glen A.; Ros, Francisco; Hershberger, J.; Tashtoush, Hasan Journal of Organic Chemistry, 1982 , vol. 47, # 8 p. 1480 - 1483

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Citation Number: 25

Abstract

Chem. SOC. 1971, 93, 4316. yield in 3.5 h) and a more severe retardation by these inhibitors was observed in the dark reaction. The results are consistent with a thermally initiated electron-transfer process which can be further stimulated by irradiation. Reaction of (EtO), PO-K+ or (MeO), PO-K+ with Me&-(NO,), did not follow reaction 1. Instead, the dialkyl phosphate esters of acetone oxime were the major produds (reaction 3). The phosphate ...