Hydrogen??bonded pseudopolyrotaxanes

M Asakawa, PR Ashton, W Hayes…

Index: Asakawa, Masumi; Ashton, Peter R.; Hayes, Wayne; Janssen, Henk M.; Meijer; Menzer, Stephan; Pasini, Dario; Stoddart, J. Fraser; White, Andrew J. P.; Williams, David J. Journal of the American Chemical Society, 1998 , vol. 120, # 5 p. 920 - 931

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Citation Number: 34

Abstract

Abstract That supramolecular order on the nanometer scale in the crystalline state can be created by using both π–π stacking and hydrogen bonding interactions marks a significant development in the fields of crystal engineering and supramolecular chemistry. The design and construction of pseudorotaxane monomers (see figure) via self-assembly is described, which are then further assembled to form linear pseudopolyrotaxane columns.