Tetrahedron letters

A direct access to α-diones from oxalyl chloride

F Babudri, V Fiandanese, G Marchese, A Punzi

Index: Babudri, Francesco; Fiandanese, Vito; Marchese, Giuseppe; Punzi, Angela Tetrahedron Letters, 1995 , vol. 36, # 40 p. 7305 - 7308

Full Text: HTML

Citation Number: 71

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Cross-coupling reactions of oxalyl chloride with organocopper reagents, derived from Grignard reagents, cuprous bromide, and lithium bromide, provide a simple and straightforward method for the synthesis of symmetrical α-diones in very good yields.

~74%

~85%

~91%

~82%

~0%

~0%

Detail

~84%

~95%

~11%

~0%

~0%

Detail

~76%

~12%

Detail

Aerobic oxidation of α-hydroxycarbonyls catalysed by trichlo...

[Kirihara, Masayuki; Ochiai, Yuta; Takizawa, Shinobu; Takahata, Hiroki; Nemoto, Hideo Chemical Communications, 1999 , # 15 p. 1387 - 1388]

Dissecting the mechanism of the heat-induced phase separatio...

[Buswell, Marina; Fleming, Ian; Ghosh, Usha; Mack, Stephen; Russell, Matthew; Clark, Barry P. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 20 p. 3006 - 3017]

Oxidation of secondary alcohols with phenyltrimethylammonium...

[Sayama, Shinsei; Onami, Tetsuo Synlett, 2004 , # 13 p. 2369 - 2373]