Polyhedron

μ-Halo bridged binuclear ruthenium (III) complexes featuring pyridazine ligands: Synthesis, structure, spectral and electrochemical properties

D Pandiarajan, R Ramesh

Index: Pandiarajan, Devaraj; Ramesh, Rengan Polyhedron, 2012 , vol. 34, # 1 p. 136 - 142

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Citation Number: 6

Abstract

The reaction of [RuX3 (AsPh3) 3] and N, N-disubstituted pyridazine-3, 6-diamine in benzene under reflux afford novel binuclear, halo-bridged, ruthenium (III) complexes with the general formula [Ru2 (AsPh3) 2 (μ-X) 2X4 (L)](X= Cl or Br; L= N, N-disubstituted pyridazine-3, 6- diamine). All the complexes have been characterized by elemental analysis, spectral (UV– Vis, EPR) and electrochemical methods (CV, DPV). The electronic spectra of the ...