Molybdenum complexes containing substituted cyclopenta [l] phenanthrenyl ligand

…, A Mukhopadhyay, C Bonifacio, CC Romão

Index: Honzicek, Jan; Mukhopadhyay, Abhik; Bonifacio, Cecilia; Romao, Carlos C. Journal of Organometallic Chemistry, 2010 , vol. 695, # 5 p. 680 - 686

Full Text: HTML

Citation Number: 8

Abstract

The synthesis of new cyclopenta [l] phenanthrenyl complexes [(η5-C17H10Me)(η3-C3H5) Mo (CO) 2] and [(η5-C17H9 (COOMe) N (CH2) 4)(η3-C3H5) Mo (CO) 2] is described. Although these compounds are structural analogues their reactivity is different. Protonation of [(η5-C17H10Me)(η3-C3H5) Mo (CO) 2] gives a stable ionic compound [(η5-C17H10Me) Mo (CO) 2 (NCMe) 2][BF4] while its analogue containing both tertiary amino and ...