Synthesis and Characterization of Some Phosphazenium Chloride Salts,[R3PNH2]+ Cl−(R= phenyl, p-chlorophenyl and morpholino)

A Sivaramakrishna, MNS Rao

Index: Sivaramakrishna, Akella; Rao, M. N. Sudheendra Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2011 , vol. 41, # 2 p. 147 - 149

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Abstract

Some phosphazenium chloride salts of the type [R3PNH2]+ Cl−, where R= phenyl, p- chlorophenyl and morpholino, were synthesized by the reaction of the corresponding phosphiniminocyclotrithiazene compounds (R3PNS3N3) with diphenyldichlorosilane in acetonitrile. All the products were characterized by analytical and spectroscopic data. The single crystal X-ray structure of [Ph3PNH2]+ Cl− was reinvestigated with one mole of ...