Unique Steric Effect of Geminal Bis (silane) To Control the High Exo-selectivity in Intermolecular Diels–Alder Reaction

Z Liu, X Lin, N Yang, Z Su, C Hu, P Xiao…

Index: Junker, Christopher S.; Welker, Mark E.; Day, Cynthia S. Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8155 - 8165

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Citation Number: 5

Abstract

... Chem. Soc. All Publications/Website. Select a Journal or Book. ... J. Am. Chem. Soc. ... For example, conformationally restricted cyclic s-cis dienophiles(8) and organometal-substituted bulky dienophiles(9) have been used to achieve a dienophile-controlled exo-D–A reaction. ...