Flexible coordination of the carboxylate ligand in tin (II) amides and a 1, 3-diaza-2, 4-distannacyclobutanediyl

…, OA Labeodan, G Schatte, N Weinberg, AR Lewis…

Index: Dickie, Diane A.; Lee, Peter T.K.; Labeodan, Ojisamola A.; Schatte, Gabriele; Weinberg, Noham; Lewis, Andrew R.; Bernard, Guy M.; Wasylishen, Roderick E.; Clyburne, Jason A.C. Dalton Transactions, 2007 , # 27 p. 2862 - 2869

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Citation Number: 9

Abstract

A series of tin (II) amido complexes possessing m-terphenyl carboxylate ligands have been prepared. These complexes, namely [(Me3Si) 2NSn (µ-O2CC6H2Ph3)] 2,[(Me3Si) 2NSn (µ- O2CC6H3Mes2)] 2, and [(Me3Si) 2NSn (µ-O2CC6H2Mes2Me)] 2 [Mes= 2, 4, 6- trimethylphenyl], are the first structurally characterized examples of tin (II) carboxylate complexes exhibiting discrete Sn2O4C2 heterocyclic cores. Initial reactivity studies led to ...