Abstract New spiro [indeno [1, 2-b] quinoxaline-11, 2′-pyrrolidine] derivatives were prepared in high yield stereoselectively from an efficient multicomponent 1, 3-dipolar cycloaddition reaction between ninhydrin, phenylenediamine, sarcosine, and chalcones. The regiochemistry and stereochemistry of resultant cycloadducts have been determined by several 2D NMR spectroscopic techniques and X-ray single crystal diffraction. J. ...