Stereospecificity in the transformation of α-aminoacids into fluoroacids

…, S De Munari, A Panzeri, V Villa, CA Gandolfi

Index: Faustini, Franco; Munari, Sergio De; Panzeri, Achille; Villa, Vittoria; Gandolfi, Carmelo A. Tetrahedron Letters, 1981 , vol. 22, # 45 p. 4533 - 4536

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Citation Number: 39

Abstract

Abstract In the reaction of α-aminoacids with excess NaNO 2 in polyhydrogen fluoridepyridine, stereospecific substitution (ie retention of configuration) is observed with C 6 H 11 CH 2 CHNH 2 COOH, while a stereospecific rearrangment occurs in the case of phenylalanine.