e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Molecular rearrangements of excited states generated by intramolecular dioxetane scission. Photochemistry without light. Mechanistic and exploratory organic …
HE Zimmerman, GE Keck…
Index: Zimmerman,H.E. et al. Journal of the American Chemical Society, 1976 , vol. 98, # 18 p. 5574 - 5581
Abstract: A series of 1-methylene-4, 4-diphenyl-2, 5-cyclohexadienes was synthesized. Singlet oxygen reacted selectively, with the exocyclic double bond affording a parallel series of dioxetanes. Thermolysis of the dioxetanes gave, in each case, 4, 4-diphe-nyl-2, 5- cyclohexadienone, 6, 6-diphenylbicyclo [3.1. O] hex-3-en-2-one, and the ketone derived from exocyclic double bond fission (ie, acetone, acetophenone, m-methoxyacetophenone, ...
