Utilization of Me 3 SiSnBu 3 in organic synthesis: I. Generation of a stannyl anion from Me3SiSnBu3 and R4NX

M Mori, N Kaneta, N Isono, M Shibasaki

Index: Mori, Miwako; Kaneta, Naotake; Isono, Naohiro; Shibasaki, Masakatsu Journal of Organometallic Chemistry, 1993 , vol. 455, # 1-2 p. 255 - 260

Full Text: HTML

Citation Number: 0

Abstract

Abstract A metal free stannyl anion generated from Me 3 SiSnBu 3 and R 4NX in DMF reacted with an aryl halide bearing carbonyl group to produce an aryl anion via the so-called halogen-metal exchange process, which reacted with a carbonyl group to afford a cyclized product in good yield.

~1%

Photoinduced radical reactions of α-alkylated ethyl 2-oxo-1-...

[Tzvetkov, Nikolay T.; Waske, Prashant A.; Neumann, Beate; Stammler, Hans-Georg; Mattay, Jochen Tetrahedron Letters, 2008 , vol. 49, # 10 p. 1710 - 1713]

Rearrangement of suitably constituted aryl, alkyl, or vinyl ...

[Beckwith,A.L.; O'Shea,D.M.; Westwood,S.W. Journal of the American Chemical Society, 1988 , vol. 110, p. 2565]