Carbohydrate Research

Epoxide ring-opening reactions of methyl 2, 3-anhydro-hexopyranosides and a new synthesis of 2, 3-episulphides

W Kudelska, M Michalska, A Šwiatek

Index: Kudelska, Wieslawa; Michalska, Maria; Swiatek, Anna Carbohydrate Research, 1981 , vol. 90, p. 1 - 6

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Abstract

Abstract Treatment of methyl 2, 3-anhydro-4, 6-O-benzylidene-α-D-mannopyranoside (1) with 2-mercapto-5, 5-dimethyl-2-thioxo-1, 3, 2-dioxaphosphorinane (3) gave methyl 4, 6-O- benzylidene-3-(5, 5-dimethyl-2-thioxo-1, 3, 2-dioxaphosphorinanylthio)-α-D-altro- ...