Diazepines. VI. The chemistry of 3, 8??dihalo??11H??dibenzo [c, f][1, 2] diazepin??11??ones

FD Popp, RJ Dubois, AC Casey

Index: Popp,F.D. et al. Journal of Heterocyclic Chemistry, 1969 , vol. 6, p. 285 - 290

Full Text: HTML

Citation Number: 2

Abstract

Abstract The carbonyl group in the title compounds undergoes a number of reactions typical of ketones but in general is less reactive than a typical ketone. Reaction with hydrazine leads to reduction of the 5, 6-bond rather than reaction at the carbonyl group. Reduction of the carbonyl group gives rise to a rather inert carbinol. The carbonyl group appears to exert little influence on typical reactions at the 5, 6-position.