Journal of organometallic chemistry

π-Allyl-palladium-komplexe stabilisiert durch den tripodalen sauerstoffliganden [(C 5 H 5) Co {P (OMe) 2 O} 3]− II. Eliminierung statt C C-bindungsbildung bei der …

B Domhöver, W Kläui

Index: Domhoever, Bernd; Klaeui, Wolfgang Journal of Organometallic Chemistry, 1996 , vol. 522, # 2 p. 207 - 212

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Citation Number: 10

Abstract

The reaction of the complexes [LOMePd (propenyl)](1) and [LOMePd (2-methyl- propenyl)](2)(LOMe−=[C5H5) Co {P (OMe) 2O} 3]−) with sodium malonate results in the formation of the anticipated C C coupling products (2-R-C3H5) CH (CO2Et) 2 while [LOMePd {4–6-η-(3-oxo-cholestenyl)}](4) and [LOMePd {4–6-η-(cholestenyl)}](5) react with elimination to give the corresponding cholestadienes. With sodium 2- ...