Macromolecules

Synthesis and nearly monochromatic photoluminescence properties of conjugated copolymers containing fluorene and rare earth complexes

QD Ling, ET Kang, KG Neoh, W Huang

Index: Ling; Kang; Neoh; Huang, Wei Macromolecules, 2003 , vol. 36, # 19 p. 6995 - 7003

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Citation Number: 92

Abstract

A series of novel conjugated copolymers containing 9, 9-dihexylfluorene and europium complex-chelated benzoate units in the main chain had been synthesized through a three- step process, involving Suzuki coupling copolymerization, hydrolysis of benzoate units, and postchelation. The chemical structures of the copolymers were characterized by FT-IR, 1H NMR, 13C NMR, GPC, and ToF-SIMS. The copolymers exhibited relatively high glass ...