Nanostructured Dioxomolybdenum (VI) Catalyst for the Liquid??Phase Epoxidation of Olefins

…, P Neves, P Brandão, V Félix, P Ferreira

Index: Castro, Alichandra; Alonso, Joao C.; Valente, Anabela A.; Neves, Patricia; Brandao, Paula; Felix, Vitor; Ferreira, Paula European Journal of Inorganic Chemistry, 2010 , # 9 p. 1405 - 1412

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Citation Number: 6

Abstract

Abstract A new organosilica hybrid mesoporous material (HM) containing phosphane oxide surface groups was prepared via the “dual” organosilane templated co-condensation of 4- bis (triethoxysilyl) benzene and (diphenylphosphanyl) propyltriethoxysilane, followed by post-synthesis oxidation of the phosphane surface groups. The HM material was used to immobilise the [Mo (O) 2 Cl 2] complex. The resultant material (HM-Mo) is an active and ...