In situ generation of 3, 3, 3-trifluoropropanal and its use for carbon-carbon bond-forming reactions

T Yamazaki, R Kobayashi, T Kitazume…

Index: Haegele, Gerhard; Haas, Andreas Journal of Fluorine Chemistry, 1996 , vol. 76, # 1 p. 15 - 19

Full Text: HTML

Citation Number: 18

Abstract

... The Journal of Organic Chemistry. ... The fate of this unstable intermediate is most likely to lose all fluorine atoms by a repetitive addition−elimination sequence of appropriate nucleophiles at the highly positively charged terminal sp 2 carbon atom possessing two fluorine atoms. ...