Radical ion probes. Part 10. Ceric (IV) ammonium nitrate oxidation of cyclopropylarenes†

Y Wang, JM Tanko

Index: Wang, Yonghui; Tanko Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 12 p. 2705 - 2711

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Abstract

The chemistry of radical cations generated the oxidation of several cyclopropylarenes with ceric () ammonium nitrate in CHCN–CHOH is reported. For cyclopropylbenzene, the major product is 1-phenylpropane-1, 3-diyl dinitrate, arising from ring opening of the cyclopropylbenzene radical cation. Experiments with 1-cyclo

~19%

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