Tetrahedron

Palladium catalysed tandem cyclisation-anion capture processes. Part 1. Background and hydride ion capture by alkyl-and π-allyl-palladium species.

…, R Grigg, V Santhakumar, V Sridharan, P Stevenson…

Index: Burns, Barry; Grigg, Ronald; Santhakumar, Vijayaratnam; Sridharan, Visuvanathar; Stevenson, Paul; Worakun, Tanachet Tetrahedron, 1992 , vol. 48, # 34 p. 7297 - 7320

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Citation Number: 97

Abstract

A new, wide ranging, synthetically powerful, catalytic tandem cyclisation-anion capture process is proposed which depends on the rate of cyclisation of an organopalladium specifies (RPdX) onto a proximate alkene or diene being significantly faster than anion exchange and reductive elimination in the sequence RPdX→ RPdY→ RY+ Pd (0). The catalytic cyclisation-anion capture sequence is illustrated for hydride capture by a wide ...