Tetrahedron

Simple aromatic amines from Justicia gendarussa. 13 C NMR spectra of the bases and their analogues

AK Chakravarty, PPG Dastidar, SC Pakrashi

Index: Chakravarty,A.; Dastidar,P. Tetrahedron, 1982 , vol. 38, p. 1797

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Citation Number: 35

Abstract

Four simple 0-disubstituted aromatic amines have been isolated from the leaves of Justicia gendarussa Burm and characterized as 2-amino benzyl alcohol (3), 2-(2′-amino- benzylamino) benzyl alcohol (4) and their respective 0-methyl ethers 1 and 2 from 1H NMR and mass spectral analyses of the bases and their acetates. Structures 3 and 4 have also been confirmed by synthesis. Intramolecular hydrogen bonding (cf. 9, 13 and 14) has ...